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The guides are organized as follows:
Health hazards, which include routes of exposure, life threat, and environmental concerns.
Safety guidelines, which include use classification, solubility properties
in water or nonaqueous carriers, EPA toxicity category, handling and storage
precautions.
Protective clothing recommendations, which suggests the PPE that
should be used when mixing, applying, rinsing, or disposing of the pesticide
or chemical.
Emergency guidelines, which include fire and explosive hazards, spills
response and remediation, and first aid.
The following example will demonstrate the use of the guides.
With the advice of the Cooperative Extension Service, you have decided
to apply Asana™XL as a treatment for the cutworms on your field corn. Before opening the container, read the label. From the label information you
determine that this product is a restricted use pesticide, meaning that you have
to be a certified applicator or work under direct supervision of a certified applicator to apply this product. The label also tells what the formulation is.
This product is an emulsifiable concentrate that contains 0.66 lbs. of active
ingredient per gallon. The chemical name of the active ingredient is also
given as (S)-cyano(3-phenoxyphenyl)methyl-(S)-4-chloro-alpha-(1-methyl
ethyl) benzeneacetate. Its percentage of the product is 8.4%. The inert or
nonactive ingredients are not listed but their percentage of the product is listed
as 91.6%. The label also states that the product contains a xylene range aromatic solvent, EPA registration number 352-515, the signal word WARNING,
first aid instructions, environmental hazards, storage and disposal recommendations, and directions for use.
To access additional information contained in the Pesticide Guides, you
would look up the trade name in Table 1. From this table you learn that
Asana is an insecticide, which is manufactured by the Du Pont Agricultural
Products and whose common name is Esfenvalerate. The information also
includes the fact that the active ingredient is only available as an emulsifiable
concentrate. The table also tells you to consult Pesticide Guide 53 for more
information.
From Pesticide Guide 53 you find the following facts:
1) Imminent health hazards and environmental concerns
2) Toxicity of the product
3) Handling and storage precautions
© 1998 by CRC Press LLC
4) Protective equipment to use when mixing and applying the product
5) Fire and explosive hazards are present when using this product
6) Spill cleanup procedures
7) Suggested first aid treatments.
In addition to the above information you should also consult the Chemical Guides for the chemical xylene, which is the carrier fluid mentioned on the
label. To access the proper guide, first look up xylene in Table 3. From this
table you find that Chemical Guide 10 should be consulted.
The following information is given in Guide 10:
1) Imminent health hazards and environmental concerns
2) The NFPA-Hazard Rating
3) Handling and storage precautions
4) Recommendations for protective equipment when using this chemical
5) Fire and explosive hazards when using this product
6) Spill cleanup procedures
7) Suggested first aid treatments.
Read the label very carefully. Most labels contain most of the information needed to use the product safely. However, if the label is vague, missing,
or illegible or if an emergency occurs, you will need to consult these tables
and guides.
It is not unusual for a pesticide user, even a trained and certified one, to
grab a container of pesticide without reading the label. At one time or another, virtually every pesticide user has identified a product by the color or
general configuration of the label. It's a relatively common occurrence, but
certainly not a safe business practice. Labels of the same color and general
makeup may contain very different ingredients. How would you know if the
pesticide is too toxic or hazardous to be used safely under your intended conditions? How do you know the formulation is right for your intended use?
How do you know what precautions should be taken when mixing the pesticide? How do you know what protective equipment to wear when applying
the material? YOU DON'T - unless you read the label and, when necessary,
consult the following tables and guides.
© 1998 by CRC Press LLC
PESTICIDE AND
CHEMICAL
TABLES
© 1998 by CRC Press LLC
ERRATA
Agrochemical and Pesticide Safety Handbook
Michael Waxman
Please note that this listing contains revised Guide Numbers that supercede those in Table 1.
Trade Name
2 Plus 2
AAtack
Aaterra
AAtrex
Abate
Acarol
Accel
Accelerate
Accent
Access
Access and Triclopyr
Acclaim IEC
Accord
Acrobat
Actellic 5E
Afugan
Agri-Mek
Alanap-L
Aliette
Ally
Ambush
Amdro
Amiben
Amid Thin W
Amitrol T
Amizol Industrial
Ammo 2.5EC
Andalin
Ansar
Anthio
Antor 4ES
Anvil
Apollo SC
Apron 25W
Apron-Terraclor
Aqua Kleen
Aquathol K
Aquazine
Arbotect
Argold
Arrosolo 3-3E
Arsenal
Arsenal Forestry
Granule
© 1998 by CRC Press LLC
New Guide Number
61
61
35-DG, L, WP, 4-EC
61
9-5G, 58-4E 61-1SG, 2GD
61
44
1
61
61
61
61
61
61
44
30
32
61
61
61
44
61
61
61
61
61
61
61
61
34
47
61
61
61
61
61
1
61
61
61
44
61
61
Trade Name
Asana XL
Aspire
Assert
Assure
Asulox
Atratol 90
Atrazine
Authority
Avenge
Avirosan
Avitrol
B-Nine SP
Balan
Banvel
Basagran
Bayleton 50%
Baytan
Baythion
Baythroid 2
Beacon
Benlate 50
Betamix
Betanex
Betasan
Bicep
Bidrin 8
Biobit
Bladex
Blazer
Bolero
Bolstar 6
Botec
Botran 75
Bravo
Broadstrike
Bronate
Bronco
Buckle
Buctril
Buctril and Atrazine
Bueno 6
Bullet
Bumper
Butisan S
New Guide Number
53
61
4
61
61
26
61
61
4
34
61-bait, 11-PC
61
61
44
61
46
61
61
44
61
61
44
44
44
61
27
61
52
6
61
51
5
61
25
61
55
26
61
36
61
61
56
46
61
Butyrac
Cannon
Canopy
Caparol 4L
Captan 50
Captan-DCNA 60-20
Capture 2EC
Carbamult
Carzol SP
Casoron 2G, 4G
Cerone
Chiptox MCPA
Sodium
Chopper
Classic
Cobra Herbicide
Comite
Command 4EC
Commence EC
Compete
Concep II
Concert
Confirm
Cotoran
Counter
Croneton
Cropstar GB
Crossbow
Crusade
Curacron 6E
Curtail
Curtail M
(petro distill)
Cycle
Cyclone
Cycocel
Cygon 400
Cymbush 3E
Cymbush 12.5 WP
Cyprex 65-W
Cythion
D.Z.N
Dacamine 4D
Daconate 6
Daconil 2787
Dacthal W-75
Def 6
Demon
Des-I-Cate
Desiccant L-10
DeVine
Devrinol
Di-Syston
Dibrom 8
© 1998 by CRC Press LLC
41
59
61
61
5
5
52
32
10
61
4
27
61
61
4
6
44
44
61
61
61
61
61
13
32
59
61
32
54
61
4
61
18
61
32
21
61
4
32-EC, 61-D, RTU, ULV
44
61
61
25
61
50
34
1
29
61
4-EC, 61-G, DF, WP
16
50
Dimilin
DiPel
Diquat Herbicide
H/A
Dithane
Dropp 50
DSMA
Dual
Duplosan KV
Dyfonate EC/G
Dylox 80% SP
Dyrene
Endocide
Endothal Turf
Herbicide
Envert 171
Eptam
Eradicane E
Escort
Esteron 99
Etan 3G
Ethrel Plant
Regulator
Evik
Evital
Express
Extrazine 11
Fallow Master
Far-Go
Finesse
Folex 6-EC
Force
Formula 40
Freedom
Frigate
Frontier
Fruitone CPA
Fruitone N
Furadan
Fusilade 2000
Galaxy
Galben
Gallery
Germate Plus
Glean
Gnatrol
Goal
Gramoxone
Guthion
Harmony Extra
Harvade 5F
Herbicide 273
Hinder
Hivol-44
61
61
33
61
61
61
44-EC, 61-G
44
12
23
44
2
1
36
61
61
61
61
49
4
61
61
61
52
4
61
61
37
57
6
59
4
39
61
61
17
61
6
61
61
61
61
61
44
18
14
61
61
1
44
61
Hoelon 3EC
Horizon IEC
Hydrothol
Hyvar
Illoxan
Image
Imidan 50
Javelin WG
Karate
Karmex DF
Kelthane
Kerb 50W
Knox Out 2FM
Krenite S
Krovar DF
Kryocide
Laddok
Landmaster
Lannate
Lariat
Larvin
Lasso
Lexone
Londax
Lorox
Lorsban
Maneb
Manzate
Marksman
Metasystox-R
Microthiol Special
Mitac
Mocap
Mocap Plus EC
Monitor
Morestan
N-Serve E
NAA-800
Nemacur EC/G
New Lorox Plus
Nimrod
Nortron
Nova 40W
Nutra-Spray Copophos
Omite
Option IEC
Orbit
Ordram EC/G
Ornamite
Orthene
Oust
Paarlan E.C.
Passport
© 1998 by CRC Press LLC
27
44
1
61
27
61
34
61
20
44
43
61
61
48
61
61
26
4
17
55
35
59
61
47
61
40
61
61
61
50
61
38
15
13
15
45
4
44
13
61
61
7
44
61
6
61
46
44-EC, 61-G
6
61
61
61
4
Penncap-M
Penncozeb
Pinnacle
Pix
Plantvax 75W
Poast
Pondmaster
Pounce G/EC/WP
Pramitol 25E
Pramitol 5PS
Prefar 4-E
Prep
Preview
Prime +
Princep
Probe
ProGibb Plus
Promalin
Prostar 4E
ProVide
Prowl
Pursuit
Pursuit Plus
Pyramin
Rally 40W
Ramrod
Ramrod and Atrazine
Ranger
Reflex 2LC
Reldan D
Release
Rely
Rescue
Rhomene
Rhonox
Ridomil plus Bravo W
Ridomil
Ridomil MZ
Ridomil G/PC
Ro-Neet 6-E
Ronilan
Rotate
Roundup
Rovral
Roxion
Royal MH-30
RTU-PCNB
RTU-VitavaxThiram
Rubigan
RyzUp
Salute 4EC
Scepter
52
61
61
61
61
46
44
61
6
6
44
4
61
6
61
44
61
44
44
61
44-EC, 61-DG
61
61
61
44
42
60
4
44
61
61
3
39
27
39
3
44
46
61
61
61
61
44-EC, 61-D-Pak
61
32
61
61
39
44
61
61
61
Scepter OT
Scout X-TRA
Sencor
Sevin
Showdown
Sinbar
Solicam
Sonalan
Spike 20P
Squadron
Stam 80EDF
Stampede CM
Starfire
Stinger
Stomp
Storm Herbicide
Strel 4E
Sulfur Alfa
Sulv
Supracide 2
Surflan
Sutan +
Sutazine +
Talon-G
Tandem
Telar
Telone C-17
Telone II
Temik 15G
Terraclor
Terrazole 25%
E-Ornamental
Terrazole 35%
WP-Turf
Tersan 1991
Thimet 15-G, 20G
Thiodan EC/WP
Thiolux DF
Thistrol
Thistrol and 2,4-D
© 1998 by CRC Press LLC
6
24
61
31
61
61
61
44
61
7
44
61
18
61
44
6
44
61
6
17
61
61
26
32
40
61
22
19
29
61
4
35
61
14
2
61
61
61
Tillam 6-E
Tiller
Tilt
Topsin M 70W
Tordon 22K
Tordon RTU
Torpedo
Tre-Hold Sprout
Inhibitor
Treflan EC
Treflan MTF
TRI-4
Tri-Scept
Trident II
Trigard
Triple-Noctin L
Tupersan
Turbo 8EC
Turfcide
Vapam
VectoBac
Velpar
Vendex
Vitavax-200
Vitavax-75W
Vitavax-34
Vitavax-PCNB
Volck Supreme Spray
Vorlex
Vydate L
WeatherBlok
Weedar 64
Weedmaster
Weedone 170
Weedone 2,4-DP
Weedone LV6
Whip 1EC
Whip 360
Ziram
Zorial Rapid 80
61
44
46
61
61
47
44
61
34
61
61
44
61
61
61
61
61
61
61
61
4
8
39-200,
61-75W
61
39
61
19
17
32
6
61
36
36
61
44
44
28-FL, 45-WP
61
Table 1. Pesticides Listed Alphabetically by Trade Name
Trade Name
Common Name
2 Plus 2
AAtack
MCPP and 2,4-D
Thiram
Aaterra
Etridazole
AAtrex
Abate
Atrazine
Temephos
Acarol
Accel
Accelerate
Accent
Access
Access and Triclopyr
Acclaim IEC
Accord
Acrobat
Bromopropylate
Benzyladenine and Gibberellins
Endothall
Nicosulfuron
Picloram
Picloram and triclopyr
Fenoxaprop-ethyl
Glyphosate
Dimethomorph
Actellic 5E
Afugan
Agri-Mek
Alanap-L
Aliette
Pirimiphos-methyl
Pyrazophos
Abamectin
Naptalam
Fosetyl-Aluminum
© 1998 by CRC Press LLC
Guide
Number a
87
91
49-DG, L,
WP, 5-EC
91
15-SG, 834E
100
64
1
100
100
99
61
92
91
60
42
44
106
90
Manufacturer
Fermenta
Rhone-Poulenc
Uniroyal
Ciba-Geigy
American Cyanamid
Company
Ciba-Geigy
Abbott
Altochem
DuPont
DowElanco
DowElanco
Hoechst
Monsanto
American Cyanamid
Company
ICI
Hoechst
Merck
Uniroyal
Rhone-Poulenc
Formulations b
Category
CAS Number c
Herbicide
Fungicide, Seed
Protectant
Soil Fungicide
Liquid
DF, WP
NA
137-26-8
D, EC, G, WP
2593-15-9
Herbicide
Insecticide
DG, EC, L, WP
EC, G
1912-24-9
3383-96-8
Acaricide
Plant Growth Regulator
Desiccant
Herbicide
Herbicide
Herbicide
Herbicide
Herbicide
Fungicide
EC
LC
18181-80-1
NA
LC
WDG
EC
EC
EC
EC
EC, WP
129-67-9
111991-09-4
NA
NA
66441-23-4
1071-83-6
110488-70-5
Insecticide
Fungicide
Insecticide, miticide
Herbicide
Fungicide
E
EC
EC
Liquid
WDG
29232-93-7
13457-18-6
71751-41-2
132-66-1
39148-24-8
Michael F. Waxman
Table 1. Pesticides Listed Alphabetically by Trade Name
Trade Name
Common Name
Guide
Number a
89
60
100
Manufacturer
Ally
Ambush
Amdro
Metsulfuron methyl
Permethrin
Hydramethylnon
Amiben
Amid Thin W
101
89
Amitrol T
Amizol Industrial
Ammo 2.5 EC
Andalin
Chloramben
Naphthaleneacet-amide
(NAAm and NAD)
Amitrole
Amitrole
Cypermethrin
Flucycloxuron
DuPont
ICI
American Cyanamid
Company
Rhone-Poulenc
Rhone-Poulenc
92
92
89
89
Rhone-Poulenc
Rhone-Poulenc
FMC
Uniroyal
Ansar
Anthio
MSMA
Formothion
92
48
Fermenta
Sandoz
Antor 4ES
Anvil
Apollo SC
Apron 25W
Apron-Terraclor
Aqua Kleen
Aquathol K
Aquazine
Arbotect
Argold
Diethatyl Ethyl
Hexaconazole
Clofentezine
Metalaxyl
Metalaxyl and PCNB
2,4-D Butoxyethyl ester
Endothall, dipotassium salt
Simazine
Thiabendazole
Cinmethylin
69
103
89
91
103
94
1
105
92
91
Arrosolo 3-3E
Molinate and Propanil
60
NOR-AM
Zeneca
NOR-AM
Ciba-Geigy, Uniroyal
Uniroyal
Phone-Poulenc
Atochem
Ciba-Geigy
Merck
American Cyanamid
Company
ICI
© 1998 by CRC Press LLC
Formulations b
Category
CAS Number c
Herbicide
Insecticide
Insecticide
DF
EC
G
74223-64-6
52645-53-1
67485-29-4
Herbicide
Plant Growth Regulator
Herbicide
Herbicide
Insecticide
Insecticide, ascaricide
Herbicide
Ascaricide, Insecticide
Herbicide
Fungicide
Miticide
Fungicide
Fungicide
Herbicide
Herbicide
Herbicide
Fungicide
Herbicide
DS, G
W
133-90-4
86-86-2
SP, DG, LS, WP, F
SP, DG, LS, WP, F
EC
DC
61-82-5
61-82-5
52315-07-8
113036-88-7
L, SG
EC, ULV
2163-80-6
2540-82-1
ES
EC
SC
D, FL,W
D
G
G
WP, WDG, liquid, G
Liquid
EC
38727-55-8
79983-71-4
74115-24-5
57837-19-1
NA
1929-73-3
129-67-9
122-34-9
148-79-8
87818-31-3
Herbicide
EC
NA