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Basic Principles
the linear momentum equation, (2–32), reduces to a balance between body and surface
forces,
∇ · T + ρg = 0,
(2–58)
whereas the thermal energy equation reduces to the form (2–57). Although the equations are
thus considerably simplified for a stationary fluid, the basic problem of requiring constitutive
equations for T and q remains.
In this section, we consider an isothermal, stationary fluid. In this case, from thermodynamics, we know that the only surface force is the normal thermodynamic pressure, p.
The pressure at a point P acts normal to any surface through P with a magnitude that is
independent of the orientation of the surface. That is, for a surface with orientation denoted
by the unit normal vector n, the surface-force vector t(n) takes the form
t(n) = −n p.
(2–59)
The minus sign in this equation is a matter of convention: t(n) is considered positive
when it acts inward on a surface whereas n is the outwardly directed normal, and p is taken
as always positive. The fact that the magnitude of the pressure (or surface force) is independent of n is “self-evident” from its molecular origin but also can be proven on purely
continuum mechanical grounds, because otherwise the principle of stress equilibrium,
(2–25), cannot be satisfied for an arbitrary material volume element in the fluid. The form
for the stress tensor T in a stationary fluid follows immediately from (2–59) and the general
relationship (2–29) between the stress vector and the stress tensor:
T = − pI.
(2–60)
In other words, in this case T is strictly diagonal:
⎛
−p
T=⎝ 0
0
0
−p
0
⎞
0
0⎠ .
−p
Equation (2–60) is the constitutive equation for the stress in a stationary fluid.
Substituting (2–60) into the force balance (2–58), and noting that
∇ · T = ∇ · (− pI) = −∇ p,
we obtain the fundamental equation of fluid statics:
ρg − ∇ p = 0.
(2–61)
It follows that the presence of a body force leads to a nonzero gradient of pressure parallel to
the body force even in a stationary fluid. Indeed, it is well know that the pressure increases
with depth under the action of gravity. Provided the fluid density remains constant, the
pressure increases linearly with depth
p(z) = p0 + ρgz
(2–62)
where p0 is a reference pressure at the vertical position, z = 0, and z increases with depth.
If we consider any arbitrary volume element from within a larger body of stationary fluid, it,
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F. Fluid Statics – The Stress Tensor for a Stationary Fluid
is evident that there must be an exact balance between the total body force and the pressure
forces acting on the volume element. This balance can be easily demonstrated for a volume
element in the shape of a vertical cylinder of fluid, say between z = z 1 and z = z 2 . The net
pressure force acting on the ends acts upward and has a magnitude
[ p(z 2 ) − p(z 1 )]π R 2 .
This is precisely equal to the total downward body force (ρg times the volume), namely,
ρg(π R 2 )(z 2 − z 1 ).
It is the increase of the hydrostatic pressure with depth that is responsible for the buoyant
force on any body that is immersed within the fluid. If we consider a cylindrical body of
radius R and length L that is oriented vertically, there is a net upward force that is due to
the increase of the hydrostatic pressure with depth, which is the same as that acting on the
column of fluid above, i.e.,
ρg(π R 2 )L .
The net downward force that is due to gravity is
ρs g(π R 2 )L ,
where ρs is the density of the body. Hence, the net force on the cylinder is
F = (ρs − ρ)g(π R 2 )L ,
which may be either up or down depending on whether the density ρs is smaller or larger,
respectively, than the density of the fluid. Although this result was derived for a circular
cylinder that is oriented vertically, it can be generalized to bodies of arbitrary shape.
For any arbitrarily shaped body of density ρs immersed in a fluid of density ρ, there is
a net upward force that is due to the increase of hydrostatic pressure with depth, which is
ρg (volume of the body).
When combined with the direct body force on the body that is due to gravity, this leads to
a net “buoyancy” force,
(ρ − ρs ) g (volume of body),
(2–63)
for a body of arbitrary shape. This is known as Archimedes’ principle. It is important to note
that the presence of a nonzero force on a body immersed in a fluid means that the body (and
thus the fluid around it) will move unless the body is acted on by some additional force.
The condition for zero motion is that the density of the body must equal that of the fluid,
ρ = ρs .
A body satisfying this condition is called “neutrally buoyant.”
We can also interpret Eq. (2–61) as a necessary condition for the fluid to remain motionless. In particular, the hydrostatic balance between ρg and ∇ p can be satisfied only if the
pressure gradient is colinear with (or in the same direction as) the body force, ρg. If there is
a component of ∇ p in any other direction, the fluid must flow. This observation allows us
to examine certain fluid configurations to determine whether they are stable or will evolve
by means of motion of the fluid to some other configuration. To see how this works, we can
begin with an example for which the result will be obvious. Let us consider a horizontal layer
of liquid, within an open cylindrical container, which we assume to initially have a surface
elevation that is raised at the edges and lower in the middle, as sketched in Fig. 2–6.15 Our
intuition probably tells us that such a configuration cannot exist as a stable, stationary state
with no fluid motion, but that fluid will flow from the outer edge toward the middle until
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Basic Principles
Interface
g
Hydrostatic
pressure
increases
with distance
from interface
Contours of
constant
hydrostatic
pressure
B
A
B
Figure 2–6. A sketch of the contours of hydrostatic pressure in a body of liquid within a cylindrical
container when the upper interface is depressed in the center and raised at the walls as shown. As discussed
in the text, the fact that the horizontal component of the pressure gradient is nonzero implies that this fluid
configuration is unstable and will undergo spontaneous motion from the walls toward the center (i.e., in
the direction of decreasing hydrostatic pressure in any horizontal plane) until the contours of hydrostatic
pressure are all horizontal and the upper interface is also flat and horizontal.
the depth of the fluid is uniform everywhere in the container. What makes this happen? The
hydrostatic pressures in the fluid layer create a horizontal pressure gradient, which cannot be
balanced by ρg, and thus the fluid flows in such a way as to produce a fluid layer of uniform
depth. Let us suppose that the pressure at all points on the upper free surface of the fluid
layer is the ambient pressure of air at the conditions of the experiment16 and that the fluid is
motionless. Then, because the depth of the liquid is larger near the outer edge and smaller in
the middle, it is clear that the hydrostatic pressure near the bottom of the container at point
B (near the outer edge) would be larger than the hydrostatic pressure at point A. Hence,
the fluid could not remain motionless in the configuration shown in Fig. 2–6, because there
would then be a horizontal pressure gradient that would drive fluid motion from B toward
A. This motion will continue until the depth is the same at every point, at which stage the
horizontal hydrostatic pressure gradient will completely vanish. It may be noted that the
hydrostatic pressure gradient in the horizontal direction will diminish as the surface flattens,
and thus we may expect the flow rate to decrease with time. It should also be emphasized that
we cannot calculate the actual flow by using the hydrostatic pressure gradients. The flow will
actually cause changes in the pressure distribution, and thus the flow too will be different
in detail from what we would calculate from the hydrostatic pressure gradient alone.
Another example of the qualitative usefulness of thinking about hydrostatic pressure
distributions occurs for a drop that is initially placed on a flat surface, as illustrated in
Fig. 2–7. We shall later see that interfacial tension at the interface between the drop and
surrounding air, as well as line tension at the solid/liquid/gas contact line can play a role
in the dynamics of such a drop. For now we assume that these factors play a negligible
role17 and concentrate on the role of the gravitational force on the drop, which we initially
imagine to be motionless. As we have seen, this leads to a hydrostatic pressure distribution
within the drop. With an initial configuration, such as that shown in Fig. 2–7, there would
be a horizontal pressure gradient within the drop, with the largest hydrostatic pressure at the
center where the drop is highest and the lowest pressures at the outer rim where the height
goes to zero. The drop cannot therefore be motionless because the horizontal pressure
gradient will produce motion of the fluid within the drop, causing the drop to spread on the
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F. Fluid Statics – The Stress Tensor for a Stationary Fluid
Interface
g
Air
Contours of constant
hydrostatic pressure
Drop
Solid substrate
Figure 2–7. A sketch of the contours of constant hydrostatic pressure within a drop that is initially placed on
a flat surface in air. As discussed in the text, the fact that the horizontal component of the pressure gradient
is nonzero implies that this fluid configuration is unstable and will undergo a spontaneous “spreading”
motion to decrease the hydrostatic pressure gradients in any horizontal plane. In this case, this process will
continue indefinitely but at a decreasing rate as the contours of hydrostatic pressure become increasingly
horizontal and flat. If the edge of the drop encounters container walls these will stop further spread and the
drop will continue to move only until it has filled the container to a constant depth.
solid substrate. Assuming that interfacial tension and contact line forces can be neglected,
as stated previously, the drop will continue to spread until it either encounters the bounding
walls of a container (at which point it will again flow until it achieves a fluid layer of uniform
depth) or until it thins to molecular dimensions when other nonhydrodynamic effects will
come into play. Again, the rate of spread is expected to diminish with time as the horizontal
component of the hydrostatic pressure gradient decreases.
A similar dynamics will occur at the “nose” or front of any fluid layer that has a
density ρ1 that exceeds the density ρ2 of a surrounding fluid. An important example from
geophysics is the so-called “gravity current” that occurs with a fluid configuration such as
that sketched in Fig. 2–8. In the geophysical examples, fluid 1 may contain a heavier solid
phase, but in any case, its density exceeds that of surrounding fluid 2. As a consequence
there is a horizontal hydrostatic pressure gradient near the nose, from a larger pressure
at A to a smaller pressure at B, and the heavy fluid, 1, must move from left to right,
displacing the lighter fluid, 2, as it does. In this case, the fact that flow is accompanied by
modifications of the pressure distribution in the fluid is very obvious, because the hydrostatic
pressure distribution in fluid 2 has no horizontal component, even though it must clearly
undergo motion in the horizontal direction as the gravity current propagates from left to
right.
Upper free
surface
g
ρ2 < ρ 1
Interface
ρ1
A
B
Figure 2–8. A sketch of the profiles of constant hydrostatic pressure near the “nose” of a gravity current.
Because of the horizontal gradients of hydrostatic pressure within the nose region, it will propagate to the
right, displacing the exterior fluid as it goes.
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Basic Principles
To emphasize again, the preceding arguments are useful only in identifying systems in
which flow will occur as a consequence of variations in the hydrostatic pressure that cannot
be balanced by a body force. To analyze any details of the motion, we would have to solve
the equations of motion to determine the velocity distribution, u(x, t), and the pressure
p(x, t), which would be modified from the hydrostatic form because of the motion of the
fluid.
G. THE CONSTITUTIVE EQUATION FOR THE HEAT FLUX
VECTOR – FOURIER’S LAW
The simplicity of the constitutive equation for stress in a stationary fluid is due to the fact
that the only surface force in this case is the thermodynamic pressure. The constitutive
equation for the heat flux vector q is not so easy to obtain, even if we assume that the fluid
is stationary, i.e., u ≡ 0. In fact, we shall see later that, for many fluids, the form of the
constitutive equation for q is expected to be the same whether the fluid is moving or not.
However, here, for simplicity of presentation, we imagine u ≡ 0. The governing thermal
energy equation is then (2–57). To determine the constitutive equation for q, we adopt a
continuum approach in the sense that we essentially attempt to guess the relevant form.
However, we first consider the process responsible for q from a qualitative, molecular point
of view, with the goal of providing as much insight as possible for this guess.
Let us begin by recalling that q represents the flux of mean molecular kinetic energy (or
heat) that is due to the purely random component of the motions of individual molecules. In a
system with a nonzero continuum (average) velocity, heat may also be transported because
of the mean motion – and this is called transport of heat by convection. However, here,
we have assumed u = 0. Let us consider the simplest molecular (or kinetic) fluid model,
namely, that of a hard-sphere (or billiard-ball) gas in which the only molecular interactions
are due to collisions and the random molecular motions are purely translational in character.
If we focus our attention on an arbitrary surface within this fluid, it is clear that the only
possible mechanism for a flux of heat is the random interchange of hard-sphere molecules
across the surface and that this will lead to heat transfer only if there is a nonzero gradient of
temperature (or average molecular kinetic energy) with a component normal to the surface.
The fact that a molecule passing across the surface in one direction is accompanied on
average by a second molecule going in the opposite direction is guaranteed by the continuum
approximation and conservation of mass. Furthermore, in this case of a hard-sphere gas, it
is evident that the net flux of heat across a surface will be proportional to the product of the
magnitude of the temperature gradient normal to the surface, the mean free path between
successive molecular collisions, and the frequency of the molecular exchange process. Of
course, the molecular transport process for real fluids will be more complicated than for a
billiard-ball gas. Nevertheless, we conclude from our considerations of that simple model
fluid that
q = q(∇θ, terms involving higher-order spatial derivatives of θ)
(2–64)
for all real fluids; that is, the rate of heat transport by means of molecular motions is
dependent on the magnitude of temperature gradients in the fluid (and quite possibly on
higher-order spatial derivatives of θ as well). The right-hand side of (2–64) represents,
in this case, either a function of ∇θ or, possibly, a functional over the past “history” of
∇θ for the fluid point of interest. Except for simple model materials like the hard-sphere
gas, this is as much as we can deduce from our understanding of the molecular origins
of q. From this point, we must guess the constitutive form for q and ultimately judge
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G. The Constitutive Equation for the Heat Flux Vector – Fourier’s Law
the success of our guess by comparing measured and predicted temperature fields in real
fluids.
A reasonable initial guess is the simplest assumption that is consistent with the relationship (2–64); namely, that the heat flux vector, q(x, t), depends linearly on∇θ(x, t):
q = −K · ∇θ.
(2–65)
Here, K is a second-order tensor that is known as the thermal conductivity tensor, and
the constitutive equation is known as the generalized Fourier heat conduction model for
the surface heat flux vector q. The minus sign in (2–65) is a matter of convention; the
components of K are assumed to be positive whereas a positive heat flux is defined as going
from regions of high temperature toward regions of low temperature (that is, in the direction
of −∇θ).
The reader may well be curious why the particular linear form of (2–65) was chosen
because at least one other vector function is linear in ∇θ , namely β ∧ (∇θ ), where β is a
constant vector. To provide a complete answer, it is necessary to introduce two important
principles that all constitutive relations are expected to obey. The first, which is frequently
taken for granted, may be called coordinate invariance. This principle states simply that
the form of a constitutive equation must be invariant under orthogonal coordinate transformations. Underlying this principle is the obvious fact that a change in orientation or sense
of the coordinate system cannot influence the relevant physical processes and thus should
not influence the form of the constitutive equation. The second invariance requirement of
a constitutive equation is that it must also remain unchanged under a transformation in the
frame of reference of the observer, even if the frame of the observer (or the fluid) is accelerating with respect to an inertial frame. This is usually thought of as being a consequence of
the intuitive notion that the mechanical or thermal properties of a material element cannot
depend on any motion of the person observing the material and is called the principle of material objectivity. Material objectivity is a stronger requirement than coordinate invariance,
but is relevant only for constitutive equations that involve dynamical variables, such as u.
Returning to the form of the constitutive equation for q, we have seen that there are two
distinct possibilities that are linear in∇θ , namely (2–65) and β ∧ (∇θ ). In this case, the
principle of coordinate invariance is sufficient to distinguish between these two possibilities.
The reader who is experienced with vector and tensor analysis may immediately recognize
that β ∧ (∇θ ) is not an acceptable form because it consists of the vector product (or cross
product) of two vectors and is thus a pseudo-vector. A key property of a pseudo-vector is
that it changes sign if we invert the coordinate axes from a right- to a left-handed coordinate
system whereas a true vector is invariant to this transformation. In particular, if we define L as
the coordinate transformation matrix (L · LT = I when the transformation is orthogonal),
then a pseudo-vector transforms according to the rule B = (det L)L · B whereas a true
vector transforms according to A = L · A. The vector formed as the cross product of the
two vectors β ∧ (∇θ ) changes sign on inversion of coordinates and it is thus a pseudo-vector.
The heat flux vector, on the other hand, is a true vector that is invariant to such changes of
coordinate systems. One condition for satisfying coordinate invariance is that all terms in
any equation involving vectors or tensors must have the same “parity” – that is, they must
all be either true vectors or they must all be pseudo-vectors. Because q is a true vector, the
only choice for the form of a constitutive equation that is linear in ∇θ and involves ∇θ only
at the present moment in time and the same point in space as q, is (2–65). Although the
same result can be obtained formally by application of a coordinate transformation to the
terms, q, K · ∇θ , and β ∧ (∇θ ), we will be content here to accept the conclusion based on
the qualitative arguments previously outlined.
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