Bạn đang xem bản rút gọn của tài liệu. Xem và tải ngay bản đầy đủ của tài liệu tại đây (413.6 KB, 44 trang )
in the MSDS for the chemical (note that current law requires chemical producers to provide
MSDSs to those who purchase chemicals from them). An MSDS file should be maintained in
every laboratory.
Even if the chemical causing the injury is not known and the victim is unconscious so that
no direct information is available, an examination of the circumstances of the accident and an
examination of the victim’s lips, skin, mouth, and tongue could provide helpful information on
whether the victim swallowed a poisonous substance or inhaled a toxic vapor, or whether the
injury was due to absorption through the skin. If the abdomen is distended and pressing on it
causes pain, the likelihood is that a corrosive or caustic substance has been ingested. Various
other symptoms such as nausea, vomiting, or dizziness can occur if the person has ingested
or inhaled a toxic substance. If there are blisters or discoloration of the skin, then external
exposure is likely. Any information on the nature of the harmful material will be helpful to the
emergency personnel or physician who will treat the victim.
iv. Poisoning by Inhalation
1. When poisoning by inhalation is suspected, evacuate the victim to a safe area as soon
as possible. If there are fumes still suspected to be present, a rescuer should wear a
self-contained respirator. Do not take a chance which might result in a second
victim.
2. Check for unusual breath odors if the victim is breathing.
3. Loosen tight clothing around the victim’s neck and waist.
4. Maintain an open airway.
5. If the victim is not breathing, perform artificial respiration using the manual method. It is
dangerous to the person providing aid to give mouth-to-mouth artificial respiration if
the toxic material is not known.
v. Poisoning by Ingestion
1. Examine the lips and mouth to ascertain if the tissues are damaged as a possible
indicator that the poison was ingested, although the absence of such signs is not
conclusive. Check the mouth and remove any dentures.
2. If the victim is not breathing, perform manual artificial respiration.
3. If the victim becomes conscious, try to get the victim to vomit, unless it is possible
tha t the poisoning is due to strong acids, caustics, petroleum products, or hydrogen
peroxide, in which case additional injuries would be caused to the upper throat
esophagus, and larynx. Vomiting may be induced by tickling the back of the throat.
Lower the head so that the vomit will not reenter the mouth and throat. Dilute the
poison in the stomach with water or milk.
4. If the victim has already vomited, collect a sample of the vomit, if possible, for
analysis.
5. If convulsions occur, do not restrain the victim, but remove objects with which he
might injure himself or orient the victim to avoid his striking fixed, heavy objects.
6. Watch for an obstruction in the victim’s mouth. Remove if possible, but do not force
fingers or a hard object in between the victim’s teeth. If a soft pad can be inserted
between the victim’s teeth, it will protect the tongue from being bitten. A badly
bleeding tongue immensely complicates the patient’s problems.
7. Loosen tight clothing, such as a collar, tie, belt, or waistband.
8. If the convulsions cease, turn the victim on his side or face down so that any fluids in
the mouth will drain.
9. Treat for shock if the symptoms for shock are noted.
vi. Poisoning by Contact
1. If the chemical got into the victim’s eyes, check for and remove any contact lenses.
Take the victim immediately to an eyewash station (if one is not available, to a shower
or even a sink) and wash the eyes, making sure that the eyelids are held widely open.
Wash for at least 15 minutes. If the chemical is caustic rather than acidic, the victim
©2000 CRC Press LLC
2.
3.
4.
5.
may not feel as much pain and may wish to quit earlier, since an acid causes pain due
to the precipitation of a protein complex. An alkali or caustic chemical is more
dangerous than an acid as it does not precipitate the protein and continues to
penetrate the globe of the eye and may even lead to global rupture. It is imperative that
the eye be flushed out thoroughly.
Do not use an eye ointment or neutralizing agent.
If the chemical only came in contact with the victim’s exposed skin, such as the hands,
wash thoroughly until the chemical is totally removed.
If the chemical was in contact with the clothed portion of the body, remove the
contaminated clothes as quickly as possible, protecting your own hands and body,
and place the victim under a deluge shower. If the eyes were not affected initially,
protect them while washing the contaminated areas. Be careful not to damage the
affected skin areas by rubbing too firmly. Let the flowing water rinse the chemical off.
A detergent is sometimes used, but be careful not to carry the offending chemical to
other parts of the body. Be particularly careful to clean folds, crevices, creases, and
groin.
If both the eyes and portions of the body were exposed, there should preferably be a
combination eyewash and deluge shower unit available. If not, take the victim to the
deluge shower and tilt the head back, holding the eyelids widely open, and wash the
entire body.
vii. Heat Burns
First Degree (minor): Painfu l and red. No blisters. Skin elastic. Epidermis only. Minimal
swelling.
1. Apply cold water to relieve pain and facilitate healing.
2. Avoid re-exposure, as the already injured skin can be more susceptible to further
damage than normal skin.
Second Degree: Severe and painful, but no immediate tissue damage. Pale to red.
Weeping blisters, vesicles. Marked swelling. Involves epidermis and dermis.
1.
2.
3.
4.
5.
Immerse affected area in cold water to abate the pain.
Apply cold, clean cloths to the burned area.
Carefully blot dry.
Do not break blisters.
If legs or arms are involved, keep them elevated with respect to the trunk of the body.
Third Degree: Deep, severe burns, likely tissue damage. White, red, or black and dry and
inelastic tissue. No pain, involves full thickness of skin. May involve subcutaneous
tissue, muscle, and bone.
1. Do not remove burned clothing from the burned area.
2. Cover the burned area with a thick, sterile dressing or clean cloths.
3. Do not immerse an extensively burned area in cold water, because this could exacerbate the potential for shock and introduce infection. A cold pack may be used on
limited areas such as the face.
4. If the hands, feet, or legs are involved, keep them elevated with respect to the trunk of
the body.
5. Third-degree burns must be treated by a physician and/or hospital. They may need
reconstruction, skin grafting, and prolonged care. Control of infection is mandatory.
©2000 CRC Press LLC
REFERENCES
Note that many of the basic references were incorporated in the text as materials needed to
plan or facilitate an effective emergency progra m. The following are additional references
used in preparing the material.
1.
Lowery, G.G. and Lowery, R.C., Handbook of Hazard Communications and OSHA Requirements,
Lewis Publishers, Chelsea, MI, 1990.
2
Lowery, G.G. and
Chelsea, MI, 1989.
3.
Laughlin, J.W., Ed., Private Fire Protection and Detection, ISFTA 210 International Fire Training
Association, Fire Protection Publications, Oklahoma State University, Stillwater, 1979.
4.
ANSI Z358.l-1998, Emergency
Institute, New York, 1981.
5.
6.
Srachta, B.J., in Safety and Health, National Safety Council, Chicago, 1987, 50.
Steere, N.V., Fire, emergency, and rescue procedures, in CRC Handbook of Laboratory Safety, Steere,
7.
N.V., Ed., CRC Press, Cleveland, OH,1971, 15.
ANSI Z87 1-1979, Practice for Occupational
8.
National Standards Institute, New York, 1979.
Schwope, A.D., Costas, P.P., Jackson, J.O., Stull, J.O., and Weitzman, D.J., Eds., Guidelines
Lowery,
R.C.,
Right-to-Know
Eyewash
and
and
Shower
Emergency
Equipment,
and Educational
Planning,
American
Lewis
Publishers,
National
Eye and Face Protection,
Standards
American
for the Selection of Chemical Protective Clothing, 3rd ed., Arthur D. Little, Inc. for U.S. EPA and U.S.
9.
Coast Guard, Cambridge, 1987.
McBriarty J.P. and Henry,
10.
American Society for Testing and Materials, Philadelphia, 1992.
ANSI Z88.2-1980 Practices for Respiratory Protection, American National Standards Institute,
N.W.,
Eds.,
Performance of
Protective Clothing:
Fourth
Volume,
New
17.
York, 1980.
Kairys, C.J., Hazmat protection improves with equipment documentation, in Occupational Health
and Safety 56, No. 12, 20, November 1987.
Still, S. and Still, J.M., Jr., Burning issues (charts), Humana Hospital, Augusta, GA.
Schmelzer L.L.,
Emergency Procedures
and
Protocol s,
Cancer Research Safety Workshop
Workbook, Office of Research Safety, National Cancer Institute, Bethesda, MD, 1978, 106.
Gröschel, D.H.M., Dwork, K.G., Wenzel, R.P., and Schiebel, L.W., Laboratory accidents with
infectious agents, i n Laboratory Safety Principles and Practices, Miller, B.M., Gröschel, D.H.M.,
Richardson, J.H., Vesley, D., Songer, J.R., Housewright, R.D., and Barkley, W.E., Eds., American
Society of Microbiology, Washington, D.C., 1986, 261.
E dlich, R.E., Levesque, E., Morgan, R.E., Kenney, J.G., Sulboway, K.A., and Thacker, J.G.,
Laboratory personnel as first responders, in L aboratory Safety Principles and Practices, Miller, B.M.,
Gröschel, D.H.M., Richardson, J.H.,Vesley, D., Songer, J.R., Housewright, R.D., and Barkley, W.E.,
Eds., American Society of Microbiology, Washington, D.C., 1986, 279.
Emergency first aid guide, appendix 4, in Laboratory Safety Principles and Practices, Miller, B.M.,
Gröschel, D.H.M., Richardson, J.H., Vesley, D., Songer, J.R., Housewright, R.D., and Barkley, W.E.,
Eds., American Society of Microbiology, Washington, D.C., 1986, 348.
Safety in Academic Chemistry Laboratories, 5th ed., American Chemical Society Washington, D.C.,
18.
19.
20.
21.
1985.
Multimedia Standard First Aid, Student Workbook, American Red Cross, Washington, D.C., 1981.
Standard First Aid & Personal Safety 2nd ed., American Red Cross, Washington, D.C., 1979.
Adult CPR Workbook, American Red Cross, Washington, D.C., 1987.
Hafen, B.Q. and Karren, K.J., First Aid and Emergency Care Workbook, 3rd ed.,
11.
12.
13.
14.
15.
16.
22.
23.
Morton
Publishing, Englewood, CO, 1984.
Senecab, J.A., Halon replacement chemicals: perspectives on the alternatives, in Fire Technology,
28(4), 332, November, 1992.
Zurer, P.S., Looming ban on production of CFC's, Halon spurs switch to substitutes, Chemical &
Engineering News, 71(46), 12, November 15, 1993.
24.
Health answers available at http://www.healthanswers.com/ -Orbis Broadcast Group,
25.
Chicago, IL.
Halon Replacements. Technology and
symposium Series, Oct. 1997.
©2000 CRC Press LLC
Science,
Andrezej
W.
Mizolek,
Editor,
Wing
1110 Sangamon
Tsang.
ACS